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Penentuan Indeks Bias Kaca Tbzp Terdedah Ion Nd3+ Dengan Metode Sudut Brewster

机译:布鲁斯特角法测定Nb3 +离子的Tbzp玻璃偏压影响指数

摘要

__________________________________________________________________________________________ Tellurite glass is a promising material for laser applications and non-linear optics. The measurement of the refractive index is a part of the physical properties determination that is important for estimating the optical properties of glass laser. This research determined and analyzed the refractive index of tellurite-based glass TBZP dopedNd3+fabricated by melt quenching technique with composition 55TeO2-2Bi2O3-(38-x) ZnO-5PbO-xNd2O3(mol%)(x=0,5; 1; 1,5; 2; 2,5). The refractive index of glass was measured by the brewster angle method on tranverse magnetic mode (TM). On the TM mode it could be determined the brewster angle and minimum reflectance value of the glass. The results showed high refractive index of fabricated glassTBZP doped by Nd3+increasing from 1.825 to 2.081 with increasing concentrations of modifier Nd2O3from 0,5 %mol to 2,5 %mol. The addition of cations on the network structure of the glass affected to the glass structure which lead to a local change of the distribution of Bridging Oxygen (BO) and Non Bridging Oxygen (NBO) bond. The addition of Nd3+ concentration caused an increasing of the value of the parameters of physical properties such as molar mass, density, molar volume, and molar refraction.
机译:________________________________碲酸盐玻璃是用于激光应用和非线性光学的有前途的材料。折射率的测量是确定物理特性的一部分,这对于估计玻璃激光器的光学特性很重要。本研究确定并分析了通过熔体淬火技术制备的碲酸盐基玻璃TBZP掺杂Nd3 +的折射率,其组成为55TeO2-2Bi2O3-(38-x)ZnO-5PbO-xNd2O3(mol%)(x = 0,5; 1; 1,5; 2; 2,5)。玻璃的折射率通过布儒斯特角法在横向磁模式(TM)上测量。在TM模式下,可以确定玻璃的布鲁斯特角和最小反射率值。结果表明,随着改性剂Nd2O3的浓度从0.5%mol增加到2.5%mol,Nd3 +掺杂的预制玻璃TBZP的高折射率从1.825增加到2.081。在玻璃的网络结构上添加阳离子会影响玻璃结构,从而导致桥接氧(BO)和非桥接氧(NBO)键的分布发生局部变化。 Nd 3+浓度的增加导致物理性质参数的值增加,例如摩尔质量,密度,摩尔体积和摩尔折射。

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